Structure, spectral and luminescence properties of compounds of europium(III) with nicotinic acid and enrofloxacin

Polishchuk A.; Karaseva é.; Pushilin M.; Kaidalova T.; Karasev V.

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Structure, spectral and luminescence properties of compounds of europium(III) with nicotinic acid and enrofloxacin

机译：与烟酸和恩诺沙星的化合物的结构，光谱和发光性质

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The compounds of Eu(III) with nicotinic acid and enrofloxacin are synthesized. Their composition and structure are proved by the data of elemental analysis, IR and luminescence spectroscopy, powder and single crystal X-ray diffraction. By single crystal X-ray diffraction, the structure of the compound of Eu with nicotinic acid is identified as a centrosymmetric dimer with 4 carboxylate bridges of the composition Eu_2(C_6H_4NO_2)_6·4H_2O. The Stark structure of the ~5D_0-~7F_j transitions in the mixed-ligand compounds of Eu(III) with nicotinic acid and enrofloxacin is determined. The bands of IR spectra are assigned; the conclusion about the bidentate coordination of ligands is made.

机译：合成了具有烟酸和恩诺沙星的Eu（III）化合物。通过元素分析，红外光谱和发光光谱，粉末和单晶X射线衍射等数据证明了它们的组成和结构。通过单晶X射线衍射，将Eu与烟酸的化合物的结构鉴定为具有4个组成Eu_2（C_6H_4NO_2）_6·4H_2O的羧酸盐桥的中心对称二聚体。确定了Eu（III）与烟酸和恩诺沙星的混合配体化合物中〜5D_0-〜7F_j跃迁的Stark结构。分配了红外光谱的波段;得出关于配体的二齿配位的结论。

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《Journal of structural chemistry》 |2011年第2期|共6页
作者
Polishchuk A.; Karaseva é.; Pushilin M.; Kaidalova T.; Karasev V.;
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正文语种 eng
中图分类结构化学;
关键词
europium; nicotinic acid; enrofloxacin; complexes; luminescence; structure;

机译：烟酸恩诺沙星络合物发光结构;

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1. Structure, spectral and luminescence properties of compounds of europium(III) with nicotinic acid and enrofloxacin [J] . Polishchuk A., Karaseva é., Pushilin M., Journal of structural chemistry . 2011,第2期

机译：与烟酸和恩诺沙星的化合物的结构，光谱和发光性质
2. Synthesis, characterization and luminescence properties of europium(III) and terbium(III) complexes with 2-pyrazinecarboxylic acid Crystal structure of [Eu(pyca)_3(H_2O)_2] centre dot 6H_2O [J] . Svetlana V. Eliseeva, Oleg V. Mirzov, Sergey I. Troyanov Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2004,第1a2期

机译：[Eu（pyca）_3（H_2O）_2]中心点6H_2O的具有2-吡嗪羧酸的（（III）和ter（III）配合物的合成，表征和发光性质
3. Synthesis and Luminescence Spectral Properties of Mixed-Ligand Europium Compounds with Quinolinic Acid [J] . I. V. Kalinovskaya, V. E. Karasev, N. V. Efimova Russian Journal of Inorganic Chemistry . 2002,第2期

机译：喹啉酸混合配体Euro化合物的合成及发光光谱性质
4. ESR and luminescence spectral properties of europium compounds with trifluoroacetic acid [C] . I. V. Kalinovskaya, A. N. Zadorozhnaya, V. G. Kuryavyi, Asia Pacific Electron Paramagnetic Resonance/Electron Spin Resonance Symposium . 2002

机译：铕化合物与三氟乙酸的ESR和发光光谱特性
5. Laser-induced europium(III) luminescence spectroscopy as a probe of DNA structure [D] . Klakamp, Scott Leroy. 1990

机译：激光诱导的（（III）发光光谱作为DNA结构的探针
6. Synthesis Crystal Structures and Photoluminescent Properties of One-Dimensional Europium(III)- and Terbium(III)-Glutarate Coordination Polymers and Their Applications for the Sensing of Fe3+ and Nitroaromatics [O] . Sajjad Hussain, Xuenian Chen, William T. A. Harrison, 2019

机译：一维铕（III）和铽（III） - 氟化物配位聚合物的合成晶体结构和光致发光性能及其用于对Fe3 +和硝基甲族的感测的应用
7. High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties of Cs3EuSi6O15, a New Europium(III) Silicate with a Three-Dimensional Framework Structure. [O] . Meow-Yu Huang, Yi-Hsiu Chen, Bor-Chen Chang, 2006

机译：CS3EUSI6O15的高温，高压水热合成，晶体结构和发光性能，具有三维框架结构的新型铕（III）硅酸盐。
8. Effect of phosphonic acid substituents on europium(III) complex stability in acidic solutions [R] . Nash, K. L. 1990

机译：膦酸取代基对酸性溶液中铕（III）配合物稳定性的影响

Structure, spectral and luminescence properties of compounds of europium(III) with nicotinic acid and enrofloxacin

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