Solubility of porphyrin macrocycles in mixed solvents

Nikiforov M.; Golubev V.; Mamardashvili G.; Al’per G.

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Solubility of porphyrin macrocycles in mixed solvents

机译：卟啉大环在混合溶剂中的溶解度

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A method based on the statements of molecular association theory and a simple lattice model (ASL = Associated Solution + Lattice) is used to calculate the solubility of a series of porphyrin macrocycles (blood porphyrins) in binary solvents (tetrachloromethane-ethyl acetate, tetrachloromethane-methanol). Separate contributions to solubility are identified and the relative role of different factors determining the solubility dependence on the mixed solvent composition is analyzed. The calculated solubility values are in good agreement with the experimental data obtained for the studied systems by the isothermal saturation method with a spectrophotometric control of concentrations.

机译：使用基于分子缔合理论和简单晶格模型（ASL =缔合溶液+晶格）陈述的方法来计算一系列卟啉大环（血卟啉）在二元溶剂（四氯甲烷-乙酸乙酯，四氯甲烷-甲醇）。确定了对溶解度的单独贡献，并分析了确定溶解度对混合溶剂成分的依赖性的不同因素的相对作用。计算出的溶解度值与通过等温饱和度法和浓度分光光度法为研究系统获得的实验数据高度吻合。

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《Journal of structural chemistry》 |2011年第2期|共6页
作者
Nikiforov M.; Golubev V.; Mamardashvili G.; Al’per G.;
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正文语种 eng
中图分类结构化学;
关键词
solubility; porphyrin macrocycles; molecular association;

机译：溶解度;卟啉大环;分子缔合;

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专利

1. Solubility of porphyrin macrocycles in mixed solvents [J] . Nikiforov M., Golubev V., Mamardashvili G., Journal of structural chemistry . 2011,第2期

机译：卟啉大环在混合溶剂中的溶解度
2. Comment on "Measurement and Modeling of Solubility of para-tert-Butylbenzoic Acid in Pure and Mixed Organic Solvents at Different Temperatures" and "Determination of Solubility and Thermodynamic Properties of Benzophenone in Different Pure Solvents" [J] . Acree William E. Jr. Journal of Chemical and Engineering Data: the ACS Journal for Data . 2018,第12期

机译：评述“叔丁基苯甲酸在不同温度下纯和混合有机溶剂中的比例和建模和建模”，“和”二苯甲酮在不同纯溶剂中的溶解度和热力学性质的测定“
3. The Effect of Chemical Modification of the Macrocycle on the Complex Formation between Porphyrins and Metal Salts in Organic Solvents [J] . Maltceva O. V., Mamardashvili N. Zh. Russian Journal of General Chemistry . 2017,第6期

机译：宏循环化学改性对有机溶剂中卟啉和金属盐的复杂形成的影响
4. Prediction of solubilities of complex medium-sized chemicals.Solutes in pure solvents,mixed solvents and cosolvent mixtures [C] . J.Abildskov, J.P.OConnell European Symposium of the Working Party on Computer Aided Process Engineering pt.A . 2005

机译：预测复合中等化学化学化学品的溶解度。纯溶剂中的溶质，混合溶剂和共溶剂混合物
5. Solubilities of gases in physical solvents and absorption rates of carbon dioxide in a mixed solvent. [D] . Henni, Amr. 2002

机译：气体在物理溶剂中的溶解度和二氧化碳在混合溶剂中的吸收率。
6. Corrigendum: Selecting water-alcohol mixed solvent for synthesis of polydopamine nano-spheres using solubility parameter [O] . Xiaoli Jiang, Yinling Wang, Maoguo Li -1

机译：更正：使用溶解度参数选择水-醇混合溶剂合成聚多巴胺纳米球
7. Comment on “Measurement and Modeling of Solubility of para-tert-Butylbenzoic Acid in Pure and Mixed Organic Solvents at Different Temperatures” and “Determination of Solubility and Thermodynamic Properties of Benzophenone in Different Pure Solvents” [O] . William E. Acree 2018

机译：评述“叔丁基苯甲酸在不同温度下纯和混合有机溶剂中的比例和建模和建模”，“和”二苯甲酮在不同纯溶剂中的溶解度和热力学性质的测定“
8. Organo-Soluble Porphyrin Mixed Monolayer-Protected Gold Nanorods with Intercalated Fullerenes. [R] . Xue, C., Xu, Y., Pang, Y., 2012

机译：有机卟啉混合单层保护金纳米棒与插层富勒烯。

Solubility of porphyrin macrocycles in mixed solvents

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