An EPR Investigation of Conductive Polyaniline- Poly(methyl methacrylate-co-acrylic acid) Blends

K.H. Wu; Y.S. Lai; C.C. Shih

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An EPR Investigation of Conductive Polyaniline- Poly(methyl methacrylate-co-acrylic acid) Blends

机译：导电性聚苯胺-聚（甲基丙烯酸甲酯-丙烯酸）共混物的EPR研究

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A conductive blend of polyaniline (PANI) with sodium form poly(methyl methacrylate-co-acrylic acid) copolymer (PMMAA) was prepared by in situ dispersion polymerization. The PANI-PMMAA blends were characterized with UV-vis, FTIR, and electron paramagnetic resonance (EPR) spectra. The effects of PANI and temperature on the electronic properties of the PANI-PMMAA blends were studied with EPR technique. The PANI and temperature affect the intermolecular interaction between PANI and PMMAA and then determines the EPR parameters (A/B ratio, g factor, T2, ΔH_(pp), N_s, and lineshape).

机译：通过原位分散聚合制备了聚苯胺（PANI）与钠型聚甲基丙烯酸甲酯-丙烯酸共聚物（PMMAA）的导电共混物。用紫外可见光谱，FTIR和电子顺磁共振（EPR）光谱对PANI-PMMAA共混物进行了表征。用EPR技术研究了PANI和温度对PANI-PMMAA共混物电子性能的影响。 PANI和温度会影响PANI和PMMAA之间的分子间相互作用，然后确定EPR参数（A / B比，g因子，T2，ΔH_（pp），N_s和线形）。

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《Polymer Composites》 |2008年第8期|共4页
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K.H. Wu; Y.S. Lai; C.C. Shih;
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正文语种 eng
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1. An EPR Investigation of Conductive Polyaniline- Poly(methyl methacrylate-co-acrylic acid) Blends [J] . K.H. Wu, Y.S. Lai, C.C. Shih Polymer Composites . 2008,第8期

机译：导电性聚苯胺-聚（甲基丙烯酸甲酯-丙烯酸）共混物的EPR研究
2. BLENDS OF POLY(ISOBUTYL METHACRYLATE) WITH POLY(STYRENE-CO-ACRYLIC ACID) AND OF POLY(ISOBUTYL METHACRYLATE-CO-ACRYLIC ACID) WITH POLY(STYRENE-CO-N,N-DIMETHYL AMINOETHYL METHACRYLATE) [J] . Djadoun S., Hamou ASH., Karasz FE. Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems . 1996,第0期

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3. Blends of poly(isobutyl methacrylate-co-acrylic acid) with poly{styrene-co-[2-(N,N-dimethyl amino)ethyl methacrylate]} or poly(styrene-co-4-vinylpyridine [J] . HadjHamou AS, Habi A, Djadoun S European Polymer Journal . 1997,第7期

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5. An investigation of poly(lactic acid) (PLA) and maleic (MAH) anhydride graft copolymer (PLA-g-MAH) and its blends with polyethylene glycol (PEG). [D] . Ma, Wenguang. 1999

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An EPR Investigation of Conductive Polyaniline- Poly(methyl methacrylate-co-acrylic acid) Blends

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