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ePC-SAFT revised

机译:ePC-SAFT修订

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摘要

So far, the electrolyte PC-SAFT equation of state developed in Cameretti et al. (2005) has been applied to model solution densities, vapor-liquid equilibria (VLE), liquid-liquid equilibria (LLE), and solid-liquid equilibria (SLE) of solutions containing electrolytes. For that purpose, two ion-specific parameters were used to characterize any ion: the diameter of the solvated ion and the dispersion-energy parameter between ion and solvent. Dispersion was only considered between ions and solvents. Considering the small number of adjustable parameters, this approach yielded acceptable results especially for low and moderate electrolyte concentrations. However, for high salt concentrations, a distinct deviation between modeled and experimental data was observed.
机译:到目前为止,电解质PC-SAFT状态方程发达Cameretti et al。(2005)应用于模型溶液密度、气液平衡(1)、液-液平衡(米歇尔),和固液平衡(SLE)的解决方案含有电解质。ion-specific参数被用来描述任何离子:溶剂化离子的直径和分散能参数和离子之间溶剂。离子和溶剂。的可调参数,这种方法产生了特别是对于低,可以接受的结果温和的电解质浓度。高盐浓度,一个明显的偏差建模和实验数据之间的关系观察到。

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