On the predictive capabilities of CPA for applications in the chemical industry: Mulficomponent mixtures containing methyl-methacrylate, dimethyl-ether or acetic acid

Tsivintzelis Ioannis; Kontogeorgis Georgios M.

首页> 外文期刊>Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers >On the predictive capabilities of CPA for applications in the chemical industry: Mulficomponent mixtures containing methyl-methacrylate, dimethyl-ether or acetic acid

【24h】

On the predictive capabilities of CPA for applications in the chemical industry: Mulficomponent mixtures containing methyl-methacrylate, dimethyl-ether or acetic acid

机译：对注册会计师的预测功能化学工业中的应用:Mulficomponent混合物包含甲基丙烯酸甲酯,二甲醚和醋酸酸

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The predictive performance of the CPA (Cubic-Plus-Association) equation of state for applications relevant to the chemical industry is illustrated in this work. Three such applications inspired by industrial requests/interest are illustrated here, all of which involve aqueous multicomponent mixtures exhibiting vapor-liquid (VLE) and/or liquid-liquid (LLE) equilibrium. The first two cases include mixtures of methyl-methacrylate with acetone or methanol and dimethyl-ether with ethanol, respectively. In these two cases, the classical form of CPA is used. The third case involves aqueous mixtures with acetic acid, esters, ethers and alcohols, and in this case for water-acetic acid the CPA-Huron Vidal (CPA-HV) version of the model is used. For the latter binary mixture, new CPA-HV binary parameter sets are estimated using, among others, data for activity coefficients at infinite dilutions. The modeling approach is similar in all three cases, i.e. the binary parameters are solely fitted to binary data and thus all multicomponent calculations are considered predictions.

机译：注册会计师的预测性能(Cubic-Plus-Association)状态方程应用程序相关的化学工业说明在这工作。灵感来源于工业/利息的请求说明,所有这些涉及到水多组分混合物表现出汽-液(1)和/或液-液(米歇尔)平衡。前两个案例包括混合物甲基丙烯酸甲酯与丙酮或甲醇和分别与乙醇、二甲醚。这两种情况下,注册会计师的古典形式使用。与醋酸酯类、醚类、醇类,在这种情况下water-acetic酸CPA-Huron维达尔(CPA-HV)版本的模型使用。二进制参数集估计使用等其他活动系数数据无限稀释。在所有三个案例相似,即二进制仅仅安装二进制数据和参数因此所有的多组分计算考虑预测。

著录项

来源
《Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers》 |2014年第12期|2947-2969|共23页
作者
Tsivintzelis Ioannis; Kontogeorgis Georgios M.;
展开▼
作者单位

Tech Univ Denmark, Dept Chem & Biochem Engn, Ctr Energy Resources Engn CERE, DK-2800 Lyngby, Denmark;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类国际共产主义运动;
关键词
Activity coefficients; mixtures; Acetic Acid Estersbinary dataAcetic AcidsMulticomponent mixturesBinaryequations of statechemical compoundsChemical IndustryModeling;

机译：活度系数;混合物;醋酸Estersbinary dataAcetic AcidsMulticomponentmixturesBinaryequations statechemical的compoundsChemical IndustryModeling;

相似文献

外文文献
中文文献

1. Density and Excess Molar Volume of Binary Mixtures ofp-Xylene＋Acetic Acid and o-Xylene＋Acetic Acid at Different Temperatures and Pressures [J] . 杨天宇, 夏淑倩, 邸志国, 中国化学工程学报：英文版 . 2008,第002期
2. Solubilities of Isophthalic Acid in Acetic Acid + Water Solvent Mixtures [J] . CHENG Youwei, HUO Lei, LI Xi 中国化学工程学报（英文版） . 2013,第007期
3. Solubility of Glutaric Acid in Cyclohexanone, Cyclohexanol, Their Five Mixtures and Acetic Acid [J] . 宋微微, 马沛生, 樊丽华, 中国化学工程学报：英文版 . 2007,第002期
4. Preparation and shaping of solid acid SO42-/TiO2 and its application for esterification of propylene glycol monomethyl ether and acetic acid [J] . Zhixian Huang, Yixiong Lin, Ling Li, 中国化学工程学报（英文版） . 2017,第009期
5. 基于神经网络的广义预测控制及在化学反应器中应用（Generalized Predictive Control Based on Neural Networks and Application in chemical reactor） [C] . Chinese Control Conference vol.2; 20040810-13; Wuxi(CN) . 2004

机译：基于神经网络的广义预测控制及在化学反应器中应用（Generalized Predictive Control Based on Neural Networks and Application in chemical reactor）

On the predictive capabilities of CPA for applications in the chemical industry: Mulficomponent mixtures containing methyl-methacrylate, dimethyl-ether or acetic acid

摘要

著录项

相似文献

相关主题

期刊订阅