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首页> 外文期刊>Nuclear Instruments & Methods in Physics Research >Molecular size effect in the chemical sputtering of a-C:H thin films by low energy H~+ H_2~+, and H_3~+ ions
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Molecular size effect in the chemical sputtering of a-C:H thin films by low energy H~+ H_2~+, and H_3~+ ions

机译:低能H〜+ H_2〜+和H_3〜+离子化学溅射a-C:H薄膜时的分子尺寸效应

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摘要

We have experimentally determined total carbon yields per incident H atom in the energy range 36-300 eV/H for H~+, H_2~+, and H+3~+ projectiles incident normally on ~60 nm thick a-C:H films, using 2-D ellips-ometry determination of erosion crater volumes ex vacuo, the separately characterized thin film carbon density, and the incident beam current integration accumulated on target during the crater evolution. During each beam exposure, methane production was monitored using in situ quadrupole mass spec-trometry (QMS). The present total carbon yields/H for incident H_3~+ ions obtained via ellipsometry are in agreement with total mass loss measurements for H_3~+ by Balden and Roth [1] over the investigated energy range. The observed methane production per incident H for the molecular ions exhibits molecular size effects over the entire energy range investigated, confirming the trend observed in the ellipsometry-based total C yields/H.
机译:我们已经通过实验确定了正常情况下入射到〜60 nm厚aC:H薄膜上的H〜+,H_2〜+和H + 3〜+弹丸的每个入射H原子在36-300 eV / H能量范围内的总碳产率。二维椭圆度测定法可在真空条件下确定侵蚀坑的体积,单独表征的薄膜碳密度以及在坑演化过程中累积在目标上的入射束电流积分。在每次射线照射期间,使用原位四极质谱(QMS)监测甲烷的产生。通过椭圆偏光法获得的入射H_3〜+离子的当前总碳收率/ H与Balden和Roth [1]在研究的能量范围内对H_3〜+的总质量损失测量相一致。观察到的分子离子每次入射H产生的甲烷产量在所研究的整个能量范围内均表现出分子大小效应,从而证实了基于椭圆偏振法的总C产率/ H的趋势。

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